资源类型

期刊论文 911

会议视频 17

年份

2023 45

2022 57

2021 54

2020 72

2019 61

2018 43

2017 38

2016 31

2015 50

2014 51

2013 41

2012 40

2011 43

2010 47

2009 41

2008 39

2007 42

2006 36

2005 18

2004 18

展开 ︾

关键词

能源 7

技术预见 5

有限元法 4

仿真 3

一阶分析法 2

上限法 2

产业成熟度 2

优化设计 2

参数估计 2

可靠性 2

多目标优化 2

悬索桥 2

数学模型 2

数据驱动方法 2

智能制造 2

最小二乘法 2

析出强化 2

海上风电场 2

神经网络 2

展开 ︾

检索范围：

排序： 展示方式：

Fe-Mn-sepiolite as an effective heterogeneous Fenton-like catalyst for the decolorization of reactive brilliant blue

Chengyuan SU,Weiguang LI,Xingzhe LIU,Xiaofei HUANG,Xiaodan YU

《环境科学与工程前沿（英文）》 2016年 第10卷 第1期   页码 37-45 doi: 10.1007/s11783-014-0729-y

摘要： A study of the decolorization of reactive brilliant blue in an aqueous solution using Fe-Mn-sepiolite as a heterogeneous Fenton-like catalyst has been performed. The Fourier transform infrared (FTIR) spectra of the catalyst showed bending vibrations of the Fe-O. The X-ray diffraction (XRD) patterns of the catalyst showed characteristic diffraction peaks of α-Fe O , γ-Fe O and MnO. A four factor central composite design (CCD) coupled with response surface methodology (RSM) was applied to evaluate and optimize the important variables (catalyst addition, hydrogen peroxide dosage, initial pH value and initial dye concentration). When the reaction conditions were catalyst dosage= 0.4 g, [H O ]= 0.3 mL, pH= 2.5, [reactive brilliant blue] = 50 mg·L , and volume of solution= 500 mL at room temperature, the decolorization efficiency of reactive brilliant blue was 91.98% within 60 min. Moreover, the Fe-Mn-sepiolite catalyst had good stability for the degradation of reactive brilliant blue even after six cycles. Leaching of iron ions (<0.4 mg·L ) was observed. The decoloring process was reactive brilliant blue specific via a redox reaction. The benzene ring and naphthalene ring were first oxidized to open ring; these were then oxidized to the alcohol and carboxylic acid. The reactive brilliant blue was decomposed mainly by the attack of ·OH radicals including surface-bound ·OH radicals generated on the catalyst surface.

关键词： Fe-Mn-sepiolite catalyst     heterogeneous Fenton-like     reactive brilliant blue     homogeneous precipitation method     hydroxyl radical    

HTML PDF 收藏

Evaluation of precipitation behavior of zirconium molybdate hydrate

Liang ZHANG, Masayuki TAKEUCHI, Tsutomu KOIZUMI, Izumi HIRASAWA

《化学科学与工程前沿（英文）》 2013年 第7卷 第1期   页码 65-71 doi: 10.1007/s11705-013-1314-9

摘要： In the dissolution step of spent nuclear fuel, there is a world-concern problem that zirconium molybdate hydrate precipitates as a byproduct, and accumulates in some reprocessing equipments. In order to prevent this accumulation, we have developed a new method based on the controlled reaction crystallization of zirconium molybdate hydrate (ZMH) in the reprocessing solution, followed by solid liquid separation. In order to measure the particle size of ZMH, batch crystallization experiments were conducted by varying nitric acid concentration and operating temperature. In result, almost all particle sizes scatter around 1 μm on average, despite the higher concentration of nitric aid and operating temperature, and then small particles grow up as an aggregate sticking to the crystallizer. Moreover, polymorph and color changing were observed by varying the concentration of nitric acid and reaction time. These results suggest that crystal color and adhesiveness are closely related to the particle size of ZMH. And the control of nitric acid concentration and small particle growth would be the useful technique to prevent the ZMH sticking.

关键词： spent nuclear fuel     zirconium molybdate hydrate     cleaning method     accumulation    

HTML PDF 收藏

A simple and cheap method for preparation of coupled ZrO2/ZnO with high photocatalytic activities

WANG Zheng, ZHANG Bingru, LI Fengting

《环境科学与工程前沿（英文）》 2007年 第1卷 第4期   页码 454-458 doi: 10.1007/s11783-007-0072-7

摘要： The objective of this study was to prepare a new photocatalyst with high activities for degradation of organic pollutants. Coupled ZrO/ZnO photocatalyst was prepared with a simple precipitation method with cheap raw

关键词： objective     ZrO/ZnO photocatalyst     photocatalyst     precipitation     degradation    

HTML PDF 收藏

Effect of a less permeable stronger soil layer on the stability of non-homogeneous unsaturated slopes

Nabarun DEY, Aniruddha SENGUPTA

《结构与土木工程前沿（英文）》 2020年 第14卷 第6期   页码 1462-1475 doi: 10.1007/s11709-020-0674-8

摘要： Slope failure occurs due to an increase in the saturation level and a subsequent decrease in matric suction in unsaturated soil. This paper presents the results of a series of centrifuge experiments and numerical analyses on a 55° inclined unsaturated sandy slope with less permeable, stronger silty sand layer inclusion within it. It is observed that a less permeable, stronger silty sand layer in an otherwise homogeneous sandy soil slope hinders the infiltration of water. The water content of the slope just above the stronger layer increases significantly, compared to elsewhere. No shear band is found to initiate in a homogeneous sandy soil slope, whereas for a non-homogeneous slope, they initiate just above the less pervious, stronger layer. A discontinuity of the shear zone is also observed for the case of a non-homogeneous soil slope. The factor of safety of a non-homogeneous, unsaturated soil slope decreases because of the less permeable, stronger layer. It decreases significantly if this less permeable, stronger soil layer is located near the toe of the slope.

关键词： non-homogeneous slope     stronger soil layer     factor of safety     centrifuge model test     unsaturated soils    

HTML PDF 收藏

An analytical method for calculating torsional constants for arbitrary complicated thin-walled cross-sections

DU Baisong, GE Yaojun, ZHOU Zheng

《结构与土木工程前沿（英文）》 2007年 第1卷 第3期   页码 293-297 doi: 10.1007/s11709-007-0038-7

摘要： In this paper, an analytical method is proposed for calculating torsional constants for complicated thin-walled cross-sections with arbitrary closed or open rib stiffeners. This method uses the free torsional theory and the principle of virtual work to build governing equilibrium equations involving unknown shear flows and twisting rate. After changing the form of the equations and combining these two unknowns into one, torsional function, which is a function of shear flow, shear modulus, and twisting rate, is included in the governing equations as only one of the unknowns. All the torsional functions can be easily obtained from these homogeneous linear equations, and torsional constants can be easily obtained from the torsional functions. The advantage of this method is that we can easily and directly obtain torsional constants from the torsional functions, rather than the more sophisticated shear flow and twisting rate calculations. Finally, a complicated thin-walled cross-section is given as a valid numerical example to verify the analytical method, which is much more accurate and simpler than the traditional finite element method.

关键词： homogeneous     complicated thin-walled     numerical example     advantage     torsional function    

HTML PDF 收藏

Control of homogeneous charge compression ignition combustion in a two-cylinder gasoline direct injection

WANG Zhi, WANG Jianxin, SHUAI Shijin, MA Qingjun, TIAN Guohong

《能源前沿（英文）》 2007年 第1卷 第3期   页码 311-315 doi: 10.1007/s11708-007-0045-3

摘要： Homogeneous charge compression ignition (HCCI) has challenges in ignition timing control, combustion rate control, and operating range extension. In this paper, HCCI combustion was studied in a two-cylinder gasoline direct injection (GDI) engine with negative valve overlap (NVO). A two-stage gasoline direct injection strategy combined with negative valve overlap was used to control mixture formation and combustion. The gasoline engine could be operated in HCCI combustion mode at a speed range of 800–2 200 r/min and load, indicated mean effective pressure (IMEP) range of 0.1–0.53 MPa. The engine fuel consumption is below 240 g/(kW

关键词： Homogeneous     control     combustion     consumption     extension    

HTML PDF 收藏

Liquid discharge plasma for fast biomass liquefaction at mild conditions: The effects of homogeneous

Sen Wang, Shiyun Liu, Danhua Mei, Rusen Zhou, Congcong Jiang, Xianhui Zhang, Zhi Fang, Kostya (Ken) Ostrikov

《化学科学与工程前沿（英文）》 2020年 第14卷 第5期   页码 763-771 doi: 10.1007/s11705-019-1896-y

摘要： Non-thermal plasma exhibits unique advantages in biomass conversion for the sustainable production of higher-value energy carriers. Different homogeneous catalysts are usually required for plasma-enabled biomass liquefaction to achieve time-and energy-efficient conversions. However, the effects of such catalysts on the plasma-assisted liquefaction process and of the plasma on those catalysts have not been thoroughly studied. In this study, an electrical discharge plasma is employed to promote the direct liquefaction of sawdust in a mixture of polyethylene glycol 200 and glycerol. Three commonly used chemicals, sulfuric acid, nitric acid and sodium -toluene sulfate, were selected as catalysts. The effects of the type of catalyst and concentration on the liquefaction yield were examined; further, the roles of the catalysts in the plasma liquefaction process have been discussed. The results showed that the liquefaction yield attains a value of 90% within 5 min when 1% sulfuric acid was employed as the catalyst. Compared with the other catalysts, sulfuric acid presents the highest efficiency for the liquefaction of sawdust. It was observed that hydrogen ions from the catalyst were primarily responsible for the significant thermal effects on the liquefaction system and the generation of large quantities of active species; these effects directly contributed to a higher efficacy of the plasma-enabled liquefaction process.

关键词： discharge plasma     biomass liquefaction     catalyst     homogeneous catalysts    

HTML PDF 收藏

Modeling radiative effects of haze on summer-time convective precipitation over North China: a case study

Xuying WANG, Bin ZHANG

《环境科学与工程前沿（英文）》 2016年 第10卷 第4期 doi: 10.1007/s11783-016-0840-3

摘要： We modeled the impact of haze radiative effects on precipitation in North China. Shortwave heating induced by haze radiative effects would reduce heavy rainfalls. Convection was the key factor that whether precipitation was enhanced or suppressed. Precipitation was often suppressed where CAPE, RH and updraft velocities were high. The impact of haze radiative effect on summertime 24-h convective precipitation over North China was investigated using WRF model (version 3.3) through model sensitivity studies between scenarios with and without aerosol radiative effects. The haze radiative effect was represented by incorporating an idealized aerosol optical profile, with AOD values around 1, derived from the aircraft measurement into the WRF shortwave scheme. We found that the shortwave heating induced by aerosol radiative effects would significantly reduce heavy rainfalls, although its effect on the post-frontal localized thunderstorm precipitation was more diverse. To capture the key factors that determine whether precipitation is enhanced or suppressed, model grids with 24-h precipitation difference between the two scenarios exceeding certain threshold (>30 mm or<-30 mm) were separated into two sets. Analyses of key meteorological variables between the enhanced and suppressed regimes suggested that atmospheric convection was the most important factor that determined whether precipitation was enhanced or suppressed during summertime over North China. The convection was stronger over places with precipitation enhancement over 30 mm. Haze weakened the convection over places with precipitation suppression exceeding 30 mm and caused less water vapor to rise to a higher level and thus further suppressed precipitation. The suppression of precipitation was often accompanied with relatively high convective available potential energy (CAPE), relative humidity (RH) and updraft velocities.

关键词： Haze     Aerosol radiative effects     Convective precipitation    

HTML PDF 收藏

Changes in hourly precipitation may explain the sharp reduction of discharge in the middle reach of the

Lin LUO, Zhongjing WANG

《环境科学与工程前沿（英文）》 2013年 第7卷 第5期   页码 756-768 doi: 10.1007/s11783-013-0563-7

摘要： The Hekou-Longmen reach, together with local floods, is the main source area for coarse sedimentations into the Yellow River. When total rainfall slightly increased in the area, discharge dramatically decreased by 40%–70% after the year of 2000, and attracting extensive attention in the context of global climate change. High temporal resolution precipitation (timescales between 1 and 4 h) data from the June to September period from 270 rain gauges over the past three decades was mined in order to help explain the phenomenon. Each rainfall event was classified as light/moderate rain, large rain, heavy rain or rainstorm by the event’s rainfall amount, and further classified as low intensity rain, medium intensity rain and high intensity rain by the event’s rainfall intensity. The Mann-Kendall trend test was applied to detect the presence and significance of monotonic trends, and to find the change points in the mean and variance of the precipitation characteristics series, including the amount, intensity, frequency and duration of each rainfall category. Results show that although the total amount of precipitation has slightly increased, the average rainfall intensity has significantly decreased. The larger change happened in light/moderate rain events and low/medium intensity rain events, and the intensity changes have a great extent occurred around the threshold of Non-Runoff Rainfall regime, which was proposed for the approximate calculation of initial losses. Changes in rainfall distribution between different classes of the Runoff Rainfall regime in the 2000s could lead to 0.9 mm less runoff depth (17.3% of the total reduction) than the 1980–1999 period. The study indicates that changes in hourly precipitation may be responsible for the sharp reduction of discharge.

关键词： precipitation intensity     Mann-Kendall rank statistic     spatial and temporal distribution     climatic change    

HTML PDF 收藏

Synthesis and characterization of magnesium hydroxide by batch reaction crystallization

Xingfu SONG, Shuying SUN, Dengke ZHANG, Jin WANG, Jianguo YU

《化学科学与工程前沿（英文）》 2011年 第5卷 第4期   页码 416-421 doi: 10.1007/s11705-011-1125-9

摘要： Magnesium hydroxide with high purity and uniform particle size distribution was synthesized by the direct precipitation method using MgCl and NaOH as reactive materials and NaCl as additive to improve the crystallization behavior of the product. The particle size distribution, crystal phase, morphology, and surface area of magnesium hydroxide were characterized by Malvern laser particle size analyzer, X-ray diffraction (XRD), scanning electron microscope (SEM) and Branauer-Emmett-Teller (BET) method, respectively. The purity of products was analyzed by the chemical method. The effects of synthesis conditions on the particle size distribution and water content (filtration cake) of magnesium hydroxide were investigated. The results indicated that feeding mode and rate, and reaction temperature had important effects on water content and the particle size distribution of the product, and sodium chloride improved the crystallization behavior of magnesium hydroxide. The ball-like magnesium hydroxides with the particle size distribution of 6.0–30.0 μm and purity higher than 99.0% were obtained. This simple and mild synthesis method was promising to be scaled up for the industrial production of magnesium hydroxide.

关键词： magnesium hydroxide     direct precipitation method     industrial crystallization     particle size distribution    

HTML PDF 收藏

Effects of compression ratio on the combustion characteristics of a homogeneous charge compression ignition

SONG Ruizhi, ZHOU Longbao, LIU Shenghua, LI Wei, HU Tiegang

《能源前沿（英文）》 2007年 第1卷 第4期   页码 463-467 doi: 10.1007/s11708-007-0068-0

摘要： The effects of homogeneous charge compression ignition (HCCI) engine compression ratio on its combustion characteristics were studied experimentally on a modified TY1100 single cylinder engine fueled with dimethyl ether. The resul

关键词： homogeneous     cylinder     combustion     compression     dimethyl    

HTML PDF 收藏

Reactive adsorption desulfurization over a Ni/ZnO adsorbent prepared by homogeneous precipitation

Aihua KONG, Yanyu WEI, Yonghong LI

《化学科学与工程前沿（英文）》 2013年 第7卷 第2期   页码 170-176 doi: 10.1007/s11705-013-1322-9

摘要： A high-performance Ni/ZnO adsorbent was prepared by homogeneous precipitation using urea hydrolysis and characterized by N adsorption-desorption, X-ray diffraction (XRD), and scanning electron microscope (SEM). The adsorbent was applied to the deep desulfurization of gasoline and showed a high breakthrough sulfur capacity and a remarkably high volume hourly space velocity. The effects of coexisting olefins in gasoline as well as adsorptive conditions on the adsorptive performance were examined. It was found that olefins in gasoline had a slightly inhibiting effect on the desulfurization performance of the adsorbent. The optimum conditions were 673 K, 1.0 Mpa with a volume hourly space velocity of 60 h . Under the optimum conditions, ultralow sulfur gasoline could be produced and the breakthrough sulfur capacity of the adsorbent was 360 mg-s/g-sorb for the model gasoline.

关键词： nickel     reactive adsorption     desulfurization     thiophene    

HTML PDF 收藏

酯交换反应在制备生物柴油上的应用

张怀渊,宋元达

《中国工程科学》 2010年 第12卷 第1期   页码 24-29

摘要：

生物柴油因其环境友好且可再生作为矿物柴油的替代燃料而备受关注，生物柴油主要通过均相酸碱催化、脂肪酶催化、超临界法和固体酸碱催化的酯交换反应制备得到，但各种制备方法各有优劣，均相酸碱催化法反应迅速，转化率高但存在后续处理复杂，污染严重等问题；脂肪酶催化法反应条件温和，对原料中的水和游离脂肪酸不敏感，不需要过量的甲醇参与反应，后续处理工序简单，但酶的成本过高，这是制约其商业化发展的最大阻碍；超临界法是制备生物柴油的新技术，反应迅速，不需要催化剂，油脂转化率非常高，但其反应需要高温高压且能耗很大；固体酸碱催化剂

关键词： 生物柴油     酯交换反应     均相酸碱     固体酸碱     脂肪酶     超临界法    

HTML PDF 收藏

Dynamic characteristics analysis of active constrained layer damping plate with various boundary conditions

Jing LU, Yu XIANG, Qiao NI

《机械工程前沿（英文）》 2011年 第6卷 第4期   页码 449-455 doi: 10.1007/s11465-011-0240-0

摘要：

Considering the direct and converse piezoelectric effect, expressions of piezoelectric membrane internal forces in the piezoelectric constrained layer were given. The control equations of the piezoelectric constrained layer and host plate were obtained in according with the thin plate theory. Based on the layer wised principle, the integrated first order differential equation of an active constrained layer damping (ACLD) plate was derived for the simply supported boundary condition. Then, this method was expanded to the ACLD plate with cantilever boundary condition by virtue of geometric analogy method. Employing the extended homogeneous capacity precision integration approach, a high precision semi-analytical method was proposed to analyze the dynamic characteristics of the ACLD plate with various boundary conditions. The comparison with the literature results has verified the accuracy and effectiveness of the present method.

关键词： active constrained layer damping (ACLD) plate     dynamic characteristics     semi-analytical method     extended homogeneous capacity precision integration approach    

HTML PDF 收藏

of vanadium and manganese from high-manganese containing vanadium wastewater by a solvent extraction-precipitation

Zishuai Liu, Yimin Zhang, Zilin Dai, Jing Huang, Cong Liu

《化学科学与工程前沿（英文）》 2020年 第14卷 第5期   页码 902-912 doi: 10.1007/s11705-019-1887-z

摘要： High-manganese containing vanadium wastewater (HMVW) is commonly produced during the vanadium extraction process from vanadium titano-magnetite. HMVW cannot be reused and discharged directly, and is harmful to the environment and affect product quality due to heavy metals in the wastewater. The wastewater is usually treated by lime neutralization, but valuable metals (especially V and Mn) cannot be recovered. In this study, an efficient and environmentally friendly method was developed to recover valuable metals by using a solvent extraction-precipitation process. In the solvent extraction process, 98.15% of vanadium was recovered, and the V O product, with a purity of 98.60%, was obtained under optimal conditions. For the precipitation process, 91.05% of manganese was recovered as MnCO which meets the III grade standard of HG/T 2836-2011. Thermodynamic simulation analysis indicated that MnCO was selectively precipitated at pH 6.5 while Mg and Ca could hardly be precipitated. The results of X-ray diffraction and scanning electron microscopy demonstrated that the obtained V O and MnCO displayed a good degree of crystallinity. The treated wastewater can be returned for leaching, and resources (V and Mn) in the wastewater were utilized efficiently in an environmentally friendly way. Therefore, this study provides a novel method for the coextraction of V and Mn from HMVW.

关键词： high-manganese containing vanadium wastewater     solvent extraction     carbonate precipitation     vanadium titano-magnetite     valuable metal recovery    

HTML PDF 收藏

标题 作者 时间 类型 操作

Fe-Mn-sepiolite as an effective heterogeneous Fenton-like catalyst for the decolorization of reactive brilliant blue

Chengyuan SU,Weiguang LI,Xingzhe LIU,Xiaofei HUANG,Xiaodan YU

期刊论文

Evaluation of precipitation behavior of zirconium molybdate hydrate

Liang ZHANG, Masayuki TAKEUCHI, Tsutomu KOIZUMI, Izumi HIRASAWA

期刊论文

A simple and cheap method for preparation of coupled ZrO2/ZnO with high photocatalytic activities

WANG Zheng, ZHANG Bingru, LI Fengting

期刊论文

Effect of a less permeable stronger soil layer on the stability of non-homogeneous unsaturated slopes

Nabarun DEY, Aniruddha SENGUPTA

期刊论文

An analytical method for calculating torsional constants for arbitrary complicated thin-walled cross-sections

DU Baisong, GE Yaojun, ZHOU Zheng

期刊论文

Control of homogeneous charge compression ignition combustion in a two-cylinder gasoline direct injection

WANG Zhi, WANG Jianxin, SHUAI Shijin, MA Qingjun, TIAN Guohong

期刊论文

Liquid discharge plasma for fast biomass liquefaction at mild conditions: The effects of homogeneous

Sen Wang, Shiyun Liu, Danhua Mei, Rusen Zhou, Congcong Jiang, Xianhui Zhang, Zhi Fang, Kostya (Ken) Ostrikov

期刊论文

Modeling radiative effects of haze on summer-time convective precipitation over North China: a case study

Xuying WANG, Bin ZHANG

期刊论文

Changes in hourly precipitation may explain the sharp reduction of discharge in the middle reach of the

Lin LUO, Zhongjing WANG

期刊论文

Synthesis and characterization of magnesium hydroxide by batch reaction crystallization

Xingfu SONG, Shuying SUN, Dengke ZHANG, Jin WANG, Jianguo YU

期刊论文

Effects of compression ratio on the combustion characteristics of a homogeneous charge compression ignition

SONG Ruizhi, ZHOU Longbao, LIU Shenghua, LI Wei, HU Tiegang

期刊论文

Reactive adsorption desulfurization over a Ni/ZnO adsorbent prepared by homogeneous precipitation

Aihua KONG, Yanyu WEI, Yonghong LI

期刊论文

酯交换反应在制备生物柴油上的应用

张怀渊,宋元达

期刊论文

Dynamic characteristics analysis of active constrained layer damping plate with various boundary conditions

Jing LU, Yu XIANG, Qiao NI

期刊论文

of vanadium and manganese from high-manganese containing vanadium wastewater by a solvent extraction-precipitation

Zishuai Liu, Yimin Zhang, Zilin Dai, Jing Huang, Cong Liu

期刊论文